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Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted

《化学科学与工程前沿(英文)》 2022年 第16卷 第8期   页码 1268-1280 doi: 10.1007/s11705-022-2143-5

摘要: The micro-nano composite structure can endow separation membranes with special surface properties, but it often has the problems of inefficient preparation process and poor structural stability. In this work, a novel atomization-assisted nonsolvent induced phase separation method, which is also highly efficient and very simple, has been developed. By using this method, a bicontinuous porous microfiltration membrane with robust micro-nano composite structure was obtained via commercially available polymers of polyacrylonitrile and polyvinylpyrrolidone. The formation mechanism of the micro-nano composite structure was proposed. The microphase separation of polyacrylonitrile and polyvinylpyrrolidone components during the atomization pretreatment process and the hydrogen bonding between polyacrylonitrile and polyvinylpyrrolidone molecules should have resulted in the nano-protrusions on the membrane skeleton. The membrane exhibits superhydrophilicity in air and superoleophobicity underwater. The membrane can separate both surfactant-free and surfactant-stabilized oil-in-water emulsions with high separation efficiency and permeation flux. With excellent antifouling property and robust microstructure, the membrane can easily be recycled for long-term separation. Furthermore, the scale-up verification from laboratory preparation to continuous production has been achieved. The simple, efficient, cost-effective preparation method and excellent membrane properties indicate the great potential of the developed membranes in practical applications.

关键词: atomization     nonsolvent induced phase separation     bicontinuous porous structure     micro-nano composite structure     oil-water separation    

Recent advances in micro- and nano-machining technologies

Shang GAO, Han HUANG

《机械工程前沿(英文)》 2017年 第12卷 第1期   页码 18-32 doi: 10.1007/s11465-017-0410-9

摘要:

Device miniaturization is an emerging advanced technology in the 21st century. The miniaturization of devices in different fields requires production of micro- and nano-scale components. The features of these components range from the sub-micron to a few hundred microns with high tolerance to many engineering materials. These fields mainly include optics, electronics, medicine, bio-technology, communications, and avionics. This paper reviewed the recent advances in micro- and nano-machining technologies, including micro-cutting, micro-electrical-discharge machining, laser micro-machining, and focused ion beam machining. The four machining technologies were also compared in terms of machining efficiency, workpiece materials being machined, minimum feature size, maximum aspect ratio, and surface finish.

关键词: micro machining     cutting     electro discharge machining (EDM)     laser machining     focused ion beam (FIB)    

Recent advances in ultrasonic-assisted machining for the fabrication of micro/nano-textured surfaces

Shaolin XU,Tsunemoto KURIYAGAWA,Keita SHIMADA,Masayoshi MIZUTANI

《机械工程前沿(英文)》 2017年 第12卷 第1期   页码 33-45 doi: 10.1007/s11465-017-0422-5

摘要:

In this paper, the state of art of ultrasonic-assisted machining technologies used for fabrication of micro/nano-textured surfaces is reviewed. Diamond machining is the most widely used method in industry for manufacturing precision parts. For fabrication of fine structures on surfaces, conventional diamond machining methods are competitive by considering the precision of structures, but have limitations at machinable structures and machining efficiency, which have been proved to be partly solved by the integration of ultrasonic vibration motion. In this paper, existing ultrasonic-assisted machining methods for fabricating fine surface structures are reviewed and classified, and a rotary ultrasonic texturing (RUT) technology is mainly introduced by presenting the construction of vibration spindles, the texturing principles, and the applications of textured surfaces. Some new ideas and experimental results are presented. Finally, the challenges in using the RUT method to fabricate micro/nano-textured surfaces are discussed with respect to texturing strategies, machinable structures, and tool wear.

关键词: ultrasonic-assisted machining     textured surface     micro/nano-structures     functional performance    

Fabrication of micro/nano-structures by electrohydrodynamic jet technique

Dazhi WANG, Xiaojun ZHAO, Yigao LIN, Tongqun REN, Junsheng LIANG, Chong LIU, Liding WANG

《机械工程前沿(英文)》 2017年 第12卷 第4期   页码 477-489 doi: 10.1007/s11465-017-0461-y

摘要:

Electrohydrodynamic jet (E-Jet) is an approach to the fabrication of micro/nano-structures by the use of electrical forces. In this process, the liquid is subjected to electrical and mechanical forces to form a liquid jet, which is further disintegrated into droplets. The major advantage of the E-Jet technique is that the sizes of the jet formed can be at the nanoscale far smaller than the nozzle size, which can realize high printing resolution with less risk of nozzle blockage. The E-Jet technique, which mainly includes E-Jet deposition and E-Jet printing, has a wide range of applications in the fabrication of micro/nano-structures for micro/nano-electromechanical system devices. This technique is also considered a micro/nano-fabrication method with a great potential for commercial use. This study mainly reviews the E-Jet deposition/printing fundamentals, fabrication process, and applications.

关键词: electrohydrodynamic jet deposition     electrohydrodynamic jet printing     micro/nano-structures     film    

Pore structure of cementitious material enhanced by graphitic nanomaterial: a critical review

S.A. GHAHARI, E. GHAFARI, L. ASSI

《结构与土木工程前沿(英文)》 2018年 第12卷 第1期   页码 137-147 doi: 10.1007/s11709-017-0431-9

摘要: Carbon nano tubes (CNT) has been introduced as an efficient nanomaterial in order to improve the mechanical and durability properties of concrete. The effect of CNT on the microstructures of cementitious materials has been widely reported. This paper combines a critical review on the effect of CNT on the pore and microstructure of cement composite with a discussion on the porosity measurement of pastes containing CNT using mercury intrusion porosimetry techniques (MIP). It was found that, surface treatment by H SO and HNO solution forms carboxyl acid groups on CNTs’ surfaces that lead to the improvement of reinforcement. In this scope, this review paper involves analyzing the effect of CNT on the microstructure and the pore structure of cementitious materials. The existing methods of measuring the porosity of cementitious material are reviewed, in particular, the contact angle measurement is discussed in detail in which the most effective parameters and possible errors of calculation is presented.

关键词: carbon nano tubes     microstructure     porosity     mercury intrusion porosimetry     cement composite    

Strengthening of polysulfone membranes using hybrid mixtures of micro- and nano-scale modifiers

Peyman P. Selakjani, Majid Peyravi, Mohsen Jahanshahi, Hamzeh Hoseinpour, Ali S. Rad, Soodabeh Khalili

《化学科学与工程前沿(英文)》 2018年 第12卷 第1期   页码 174-183 doi: 10.1007/s11705-017-1670-y

摘要: Polysulfone (PSf) membranes were modified by either a new organic modifier (sulfonated poly(ether sulfide sulfone), SPESS) or a traditional modifier (rice hulk). These membranes were further reinforced with either multi-walled carbon nanotubes (MWCNTs) or silica nanoparticles. Having a dye rejection of 98.46%, the reinforced membranes increased more than 50% in strength but no change in solution flux was observed. The morphological and roughness studies were conducted using scanning electron microscopy and atomic force microscopy. Moreover, the PSF membranes were also characterized by differential scanning calorimetry. Modifying the membranes with organic modifier or nanofiller increases the glass transition temperature ( ). The highest and strength were observed for the PSf-SPESS-MWCNT membrane. SPESS decreases surface roughness but MWCNT increases roughness on the nanoscale. All membranes show a bimodal pore size distribution, whereas the PSf-SPESS-MWCNT membrane exhibits a relatively uniform distribution of macroscopic and microscopic pores.

关键词: polysulfone membrane     mechanical properties     micro- and nano-modification     binary and ternary system     dye removal    

Optimizing the compressive strength of concrete containing micro-silica, nano-silica, and polypropylene

Fatemeh ZAHIRI, Hamid ESKANDARI-NADDAF

《结构与土木工程前沿(英文)》 2019年 第13卷 第4期   页码 821-830 doi: 10.1007/s11709-019-0518-6

摘要: Many studies have evaluated the effects of additives such as nano-silica (NS), micro-silica (MS) and polymer fibers on optimizing the mechanical properties of concrete, such as compressive strength. Nowadays, with progress in cement industry provides, it has become possible to produce cement type I with strength classes of 32.5, 42.5, and 52.5 MPa. On the one hand, the microstructure of cement has changed, and modified by NS, MS, and polymers; therefore it is very important to determine the optimal percentage of each additives for those CSCs. In this study, 12 mix designs containing different percentages of MS, NS, and polymer fibers in three cement strength classes(CSCs) (32.5, 42.5, and 52.5 MPa) were designed and constructed based on the mixture method. Results indicated the sensitivity of each CSCs can be different on the NS or MS in compressive strength of concrete. Consequently, strength classes have a significant effect on the amount of MS and NS in mix design of concrete. While, polymer fibers don’t have significant effect in compressive strength considering CSCs.

关键词: mixture method     compressive strength     nano-silica     micro-silica     polypropylene fibers    

Antibacterial and anti-flaming PA6 composite with metathetically prepared nano AgCl@BaSO

Wei Zhang, Boren Xu, Caihong Gong, Chunwang Yi, Shen Zhang

《化学科学与工程前沿(英文)》 2021年 第15卷 第2期   页码 340-350 doi: 10.1007/s11705-020-1942-9

摘要: In this study, a facile and environmentally friendly method with low energy consumption for preparing nanoscale AgCl and BaSO co-precipitates (AgCl@BaSO co-precipitates) was developed based on the metathetical reaction. Then, the dried co-precipitates were melt-compounded with polyamide 6 (PA6) resins at a specified mass ratio in a twin-screw extruder. The results demonstrated that in the absence of any coating agent or carrier, the nanoparticles of AgCl@BaSO co-precipitates were homogeneously dispersed in the PA6 matrix. Further analysis showed that after the addition of AgCl@BaSO co-precipitates, the antibacterial performance, along with the flame-retardance and anti-dripping characteristics of PA6, was enhanced significantly. In addition, the PA6 composites possessed high spinnability in producing pre-oriented yarn.

关键词: nano AgCl@BaSO4 co-precipitates     antibacterial     flame resistance     PA6 composite     PA6 yarn    

Magnetic KIT-6 nano-composite and its amino derivatives as convenient adsorbent for U(VI) sequestration

《化学科学与工程前沿(英文)》 2023年 第17卷 第12期   页码 2037-2049 doi: 10.1007/s11705-023-2358-0

摘要: Although mesoporous silica with magnetically hybridized two-dimensional channel structures has been well studied in recent years, it remains a challenge to fabricate the counterpart with macroporous three-dimensional cubic structures since the highly acidic preparation conditions lead to dissolution of magnetic particles. Herein, we successfully prepared magnetic KIT-6 nano-composite and its amino derivatives by bearing acid-resistant iron oxide. The prepared materials exhibited excellent properties for U(VI) ions removal from aqueous solutions under various conditions. The experimental data show that the U(VI) adsorption features fast adsorption kinetics, high adsorption capacity and ideal selectivity toward U(VI). The adsorption process is of spontaneous and endothermic nature and ionic strength independence, and the adsorbents can be easily regenerated by acid treatment. Compared to pristine KIT-6, the introduction of magnetism does not reduce the efficiency of the material to remove U(VI) while exerting its role as a recovery adsorbent. The findings of this work further demonstrate the potential broad application prospects of magnetic hybrid mesoporous silica in radionuclide chelation.

关键词: magnetic nanoparticle     3D mesoporous silica     amino functionalization     adsorption of U(VI)     acid resistance    

Nano-copper ions assembled cellulose-based composite with antibacterial activity for biodegradable personal

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1544-1554 doi: 10.1007/s11705-022-2288-2

摘要: The current SARS-CoV-2 pandemic has resulted in the widespread use of personal protective equipment, particularly face masks. However, the use of commercial disposable face masks puts great pressure on the environment. In this study, nano-copper ions assembled cotton fabric used in face masks to impart antibacterial activity has been discussed. To produce the nanocomposite, the cotton fabric was modified by sodium chloroacetate after its mercerization, and assembled with bactericidal nano-copper ions (about 10.61 mg·g–1) through electrostatic adsorption. It demonstrated excellent antibacterial activity against Staphylococcus aureus and Escherichia coli because the gaps between fibers in the cotton fabric allow the nano-copper ions to be fully released. Moreover, the antibacterial efficiency was maintained even after 50 washing cycles. Furthermore, the face mask constructed with this novel nanocomposite upper layer exhibited a high particle filtration efficiency (96.08% ± 0.91%) without compromising the air permeability (28.9 min·L–1). This green, economical, facile, and scalable process of depositing nano-copper ions onto modified cotton fibric has great potential to reduce disease transmission, resource consumption, and environmental impact of waste, while also expanding the range of protective fabrics.

关键词: cellulose-based     nanocomposite     biodegradable antibacterial fabric     nano-copper ions     face masks    

面向微纳卫星自主汽化管理液氨推进系统的设计、研制和测试 Regular Article

Shu-jian Sun, Tao Meng, Zhong-he Jin,sunshujian@zju.edu.cn,mengtao@zju.edu.cn

《信息与电子工程前沿(英文)》 2019年 第20卷 第11期   页码 1516-1529 doi: 10.1631/FITEE.1800068

摘要: 提出一种面向微纳卫星的自主汽化管理液氨推进系统。相比常规冷气或液化气推进系统,提出多路平行筛孔式汽化装置和对应汽化控制方法。所提方案有效解决了液氨高汽化潜热和不易完全汽化的问题,从而发挥液氨推进剂高贮存密度和高比冲性能优势。此外,重点分析自主汽化管理液氨推进系统的工作流程及其涉及的物理化学过程和数学模型。综合考虑推力表现和能源效率,提出最优系统推力控制策略。地面测试表明,自主汽化管理液氨推进系统总重1.8 kg(包含0.34 kg液氨推进剂),比冲达到100 s,系统功耗在10 W以下。自主汽化管理液氨推进系统具有高比冲、低功耗、可实现性强、推力输出均一稳定等特点,适合微纳卫星在轨应用。

关键词: 自主汽化管理;液氨;毫牛量级推进技术;微推力;高精度轨道控制;微纳卫星    

Influence of short chain ceramides and lipophilic penetration enhancers on the nano-structure of stratum

Annett SCHROETER, Tanja ENGELBRECHT, Reinhard H. H. NEUBERT

《化学科学与工程前沿(英文)》 2013年 第7卷 第1期   页码 29-36 doi: 10.1007/s11705-013-1302-0

摘要: Oriented stratum corneum model lipid membranes were used to study the influence of the short chain ceramides (CER)[NP] and [AP] as well as the impact of the lipophilic penetration enhancer molecules oleic acid (OA) and isopropyl myristate (IPM) on the lipid nanostructure. The influence of the enhancer molecules were studied using specifically deuterated OA and IPM and neutron diffraction. H NMR spectroscopy was used to study the impact of the ceramides’ degree of order within the stratum corneum model lipid membranes. It was found that CER[NP] forms two very stable phases with high resistance against temperature increase. Phase B showed unusual hydration behavior as no water uptake of this phase was observed. The H NMR spectroscopic measurements showed that CER[NP] based ternary model system had a higher state of lamellar order in comparison to CER[AP] based lipid matrix. The studies confirmed that the short chain ceramides, particularly CER[NP], have a very high impact on the integrity of the Stratum corneum lipid bilayers. The penetration enhancer OA has not influenced the repeat distance of the model membrane based on CER[AP], and was not able to induce a phase separation in the investigated lipid matrix. However, a disorder and a fluidisation of the model membranes were observed when OA was incorporated. IPM showed the same effect but two phases (assigned as phase A and B) appeared, when IPM was used as penetration enhancer and incorporated into the model membrane. Furthermore, two arrangements of IPM were identified in phase A using deuterated IPM. A model of the nanostructure of the Stratum corneum lipid membranes is presented.

关键词: nano-structure of the stratum corneum     ceramide     penetration enhancer     model membrane     neutron diffraction     2H NMR spectroscopy    

微纳操作与表征

Yu Sun, Sergej Fatikow, Xinyu Liu

《工程(英文)》 2023年 第24卷 第5期   页码 1-2 doi: 10.1016/j.eng.2023.04.006

纳卫星微型百叶窗热控技术研究及仿真

杨娟,李运泽,王浚

《中国工程科学》 2008年 第10卷 第7期   页码 169-172

摘要:

微型百叶窗能够适当解决因体积及质量限制而引起的纳卫星内部热环境高热流密度问题。微型百 叶窗驱动的智能化控制方法是亟待解决的关键技术。在球状纳卫星动态特性模型的基础上,提出了一种模 糊PI 混合控制方法。分别在舱内仪器散热增加和减少的工况下进行控制仿真。结果表明,这种并联控制系 统较之单独使用模糊控制器和传统PID控制器在控制效果和动态特性方面更佳。

关键词: 纳卫星     微型百叶窗     模糊PI 控制器     仿真    

Preparation and photocatalytic kinetics of nano-ZnO powders by precipitation stripping process

ZHANG Dongxiang, XUE Min, XU Hang, XU Wenguo, TARASOV V

《化学科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 319-324 doi: 10.1007/s11705-008-0051-y

摘要: Ultra-fine zinc oxalate powders were prepared through a precipitation stripping method with bis(2-ethylhexyl) phosphate (HDEHP) diluted by tetrachloride carbon as the extractant, and oxalic acid ethanol aqueous solution as the re-extractant and precipitator. Zinc oxide powders were obtained by decomposing zinc oxalate powders at 450°C. The prepared zinc oxide powders were characterized by transmission electron microscope (TEM), Scanning electron microscope (SEM), Thermogravimetric analysis (TG), X-ray diffraction (XRD) and Fourier transmission infrared (FT-IR) spectrum. The photocatalytic performance of methylene blue by zinc oxide was studied based on the Langmuir model and Photo-Layer model. The results show that some zinc oxide powders were micro-multipore materials with hexagonal crystal. The particle size was around 32 nm. The photocatalytic process was the control step in the chemical reaction. The photo catalytic process followed pseudo-first order kinetics and •OH concentration inside the photo-layer in different reaction condition were calculated according to the Photo-Layer model.

关键词: 2-ethylhexyl     micro-multipore     Photo-Layer     hexagonal     methylene    

标题 作者 时间 类型 操作

Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted

期刊论文

Recent advances in micro- and nano-machining technologies

Shang GAO, Han HUANG

期刊论文

Recent advances in ultrasonic-assisted machining for the fabrication of micro/nano-textured surfaces

Shaolin XU,Tsunemoto KURIYAGAWA,Keita SHIMADA,Masayoshi MIZUTANI

期刊论文

Fabrication of micro/nano-structures by electrohydrodynamic jet technique

Dazhi WANG, Xiaojun ZHAO, Yigao LIN, Tongqun REN, Junsheng LIANG, Chong LIU, Liding WANG

期刊论文

Pore structure of cementitious material enhanced by graphitic nanomaterial: a critical review

S.A. GHAHARI, E. GHAFARI, L. ASSI

期刊论文

Strengthening of polysulfone membranes using hybrid mixtures of micro- and nano-scale modifiers

Peyman P. Selakjani, Majid Peyravi, Mohsen Jahanshahi, Hamzeh Hoseinpour, Ali S. Rad, Soodabeh Khalili

期刊论文

Optimizing the compressive strength of concrete containing micro-silica, nano-silica, and polypropylene

Fatemeh ZAHIRI, Hamid ESKANDARI-NADDAF

期刊论文

Antibacterial and anti-flaming PA6 composite with metathetically prepared nano AgCl@BaSO

Wei Zhang, Boren Xu, Caihong Gong, Chunwang Yi, Shen Zhang

期刊论文

Magnetic KIT-6 nano-composite and its amino derivatives as convenient adsorbent for U(VI) sequestration

期刊论文

Nano-copper ions assembled cellulose-based composite with antibacterial activity for biodegradable personal

期刊论文

面向微纳卫星自主汽化管理液氨推进系统的设计、研制和测试

Shu-jian Sun, Tao Meng, Zhong-he Jin,sunshujian@zju.edu.cn,mengtao@zju.edu.cn

期刊论文

Influence of short chain ceramides and lipophilic penetration enhancers on the nano-structure of stratum

Annett SCHROETER, Tanja ENGELBRECHT, Reinhard H. H. NEUBERT

期刊论文

微纳操作与表征

Yu Sun, Sergej Fatikow, Xinyu Liu

期刊论文

纳卫星微型百叶窗热控技术研究及仿真

杨娟,李运泽,王浚

期刊论文

Preparation and photocatalytic kinetics of nano-ZnO powders by precipitation stripping process

ZHANG Dongxiang, XUE Min, XU Hang, XU Wenguo, TARASOV V

期刊论文